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61.
Hao Li Pengcheng Zhang Shengquan Yu Hongyu Yang Bin Tang Fuhai Li Shuren Zhang 《Ceramics International》2019,45(9):11639-11647
Mg2(Ti1-xSnx)O4 (x?=?0–1) ceramics were prepared through conventional solid-state method. This paper focused on the dependence of microwave dielectric properties on crystal structural characteristics via crystal structure refinement, Raman spectra study and complex chemical bond theory. XRD spectrums delineated the phase information of a spinel structure, and structural characteristic of these compositions were achieved with the help of Rietveld refinements. Raman spectrums were used to depict the correlations between vibrational phonon modes and dielectric properties. The variation of permittivity is ascribed to the Mg2(Ti1-xSnx)O4 average bond covalency. The relationship among the B-site octahedral bond energy, tetrahedral bond energy and temperature coefficient are discussed by defining on the change rate of bond energy and the contribution rate of octahedral bond energy. The quality factor is affected by systematic total lattice energy, and the research of XPS patterns illustrated that oxygen vacancies can be effectively restrained in rich oxygen sintering process. Obviously, the microwave dielectric properties of Mg2(Ti1-xSnx)O4 compounds were obtained (= 12.18, ?=?170,130?GHz, ?=??53.1?ppm/°C, x?=?0.2). 相似文献
62.
Qianglong He Aiyang Wang Chun Liu Weimin Wang Hao Wang Zhengyi Fu 《Journal of the European Ceramic Society》2018,38(7):2832-2840
B4C-TiB2-SiC composites were fabricated via hot pressing using ball milled B4C, TiB2, and SiC powder mixtures as the starting materials. The impact of ball milling on the densification behaviors, mechanical properties, and microstructures of the ceramic composites were investigated. The results showed that the refinement of the powder mixtures and the removal of the oxide impurities played an important role in the improvement of densification and properties. Moreover, the formation of the liquid phases during the sintering was deemed beneficial for densification. The typical values of relative density, hardness, bending strength, and fracture toughness of the composites reached 99.20%, 32.84?GPa, 858?MPa and 8.21?MPa?m1/2, respectively. Crack deflection, crack bridging, crack branching, and microcracking were considered to be the potential toughening mechanisms in the composites. Furthermore, numerous nano-sized intergranular/intragranular phases and twin structures were observed in the B4C-TiB2-SiC composite. 相似文献
63.
64.
以法国梧桐絮为原料、KOH为活化剂,通过碳化制备多孔纤维碳材料,并在此基础上组装了超级电容器器件。通过SEM、EDS、XRD、Raman、FTIR、BET等对制备的多孔纤维碳材料进行表征,并研究了多孔纤维碳材料电极的电化学性能。结果表明:在扫描速率为50 mV·s~(-1)时,800℃下碳化制备的梧桐絮多孔纤维碳材料电极的比电容可以达到236 F·g~(-1);所组装电极在循环10 000次后,比电容仍维持原来的99.8%,表明梧桐絮多孔纤维碳材料在超级电容器领域有巨大的应用潜力。 相似文献
65.
66.
本工作以丙烯腈/衣康酸(IA)二元共聚原丝以及丙烯腈/IA/丙烯酸甲酯(MA)三元共聚原丝为研究对象,利用热重分析仪(TG)和热解-同步辐射真空紫外光电离质谱(Py-SVUV-PIMS)对其热稳定化过程进行研究。TG结果表明,氮气气氛下,二元共聚原丝(PAN/IA)和三元共聚原丝(PAN/IA/MA)分别呈现三阶段和两阶段的热分解过程,其中PAN/IA的第一和第二阶段均对应PAN线型分子链的断裂,但前者是由自由基环化反应放热引发的,后者则是由正常温度下的热分解所致,而单体MA的加入显著抑制了自由基环化反应,使得PAN原丝的热稳定化能够以单体IA诱导的离子型环化反应为主较平缓地进行,相应的热失重过程也由两阶段转变为了单阶段。Py-SVUV-MS的实验结果表明,两种共聚PAN原丝在程序升温过程中会生成包括含氮小分子、丙烯腈单体及低聚物、成环化合物在内的三类主要热解产物,对比各类产物的生成趋势和产量,推断单体MA通过降低PAN结构的规整度,使其无定形化,从而增加环化反应的引发点,促进PAN原丝向稳定的预氧丝转变,同时由典型热解产物——甲基丙烯腈的生成路径可知,MA本身并不参与PAN大分子的环化反应,属于中性共聚单体。空气气氛下,CO2的产量差异也间接证明了MA单体能够有效提升PAN纤维的固碳能力,采用三元共聚方法制得的PAN纤维热稳定性能更佳。 相似文献
67.
We investigate the effects of doping and annealing on the dielectric properties of metal ions doped TiO2 ceramics. Colossal permittivity (CP) above 104 was observed in single Nb ion doped TiO2, which was dominated by electron transport related interfacial polarization. Moreover, the CP can be dropped to 120 when simultaneously introducing Mn ion into the sample. The disappearance of CP behaviors maybe due to the multivalence of Mn which would inhibit the reduction of Ti4+ to Ti3+, and thus reduce delocalized electrons. Interestingly, the CP was recovered for the (Nb+Mn) co-doped TiO2 after post-sintering heat treatment in N2 atmosphere. The recovery of CP in the sample after annealing can be ascribed to the semiconducting grain and the insulating grain boundary, according to impedance spectroscopy. We therefore believe that this work can help us understand the mechanism of CP from a new perspective. 相似文献
68.
探讨了直纺83 dtex/114 f波浪扁平涤纶全拉伸丝(FDY)的工艺制备过程。试验证明,在熔体输送温度276~282℃,纺丝温度286~290℃,喷丝板规格DIO φ104 mm-114孔、"王"字形,环吹风压10~15 Pa,含油率1.1%~1.2%,卷绕速度3 800~4 200 m/min的工艺参数下纺制83 dtex/114 f波浪扁平涤纶FDY时,生产稳定,满卷率高,外观情况良好,袜带均匀亮丽,可批量生产。此新产品可用于制作高档布艺沙发表层面料,具有抗倒伏、色彩艳丽等功效。 相似文献
69.
49MnVS3非调质钢(/%:0.47C,0.39Si,0.90Mn,0.016P,0.050S,0.22Cr,0.09V,0.015Ti,0.011Al,0.02Ni)的生产流程为铁水预处理-60t顶底复吹转炉-LF处理-VD真空脱气-220 mm×300 mm坯连铸-控轧控冷。研究了控轧控冷工艺对49MnVS3非调质钢组织和性能的影响。φ110 mm轧材试验工艺参数:加热温度1150~1250℃、开轧温度1 0500℃、终轧温度850℃、轧后冷却速度70℃/min、冷却开始温度850℃和终止温度500℃。结果表明,试验炉次粒度提高高.5~1.0级,带状组织减轻轻0.5~1.5级,硬度、强度及塑韧性均有所提升,获得良好的强韧性匹配。 相似文献
70.
With increasing consumption of natural gas (NG), small NG reservoirs, such as coalbed methane and oil field associated gas, have recently drawn significant attention. Owing to their special characteristics (e.g., scattered distribution and small output), small-scale NG liquefiers are highly required. Similarly, the mixed refrigerant cycle (MRC) is suitable for small-scale liquefaction systems due to its moderate complexity and power consumption. In consideration of the above, this paper reviews the development of mobile miniature NG liquefiers in Technical Institute of Physics and Chemistry (TIPC), China. To effectively liquefy the scattered NG and overcome the drawbacks of existing technologies, three main improvements, i.e., low-pressure MRC process driven by oil-lubricated screw compressor, compact cold box with the new designed heat exchangers, and standardized equipment manufacturing and integrated process technology have been made. The development pattern of “rapid cluster application and flexible liquefaction center” has been eventually proposed. The small-scale NG liquefier developed by TIPC has reached a minimum liquefaction power consumption of about 0.35 kW·h/Nm3. It is suitable to exploit small remote gas reserves which can also be used in boil-off gas reliquefaction and distributed peak-shaving of pipe networks. 相似文献